MSDS for WearMax Cross Linker


Trustor Coatings, 401 North 72 nd Ave., Wausau, WI 54401
24 Hour Emergency Telephone: (715) 849-8080

Section 1. PRODUCT IDENTIFICATION

PRODUCT NAME: Wearmax Cross linker
Read the entire MSDS for a complete hazard assessment.

Section 2. HAZARDOUS INGREDIENTS AND EXPOSURE LIMITS
Substances presenting a health hazard within the meaning of the Dangerous Substances Directive 67/548/EEC

CAS
Ingredient Name Number Conc. %*
Polyfunctional aziridine 064265-57-2 99.7

Ingredients not precisely identified are either proprietary or nonhazardous.
Values are not product specifications. * Percent concentration by weight.

Section 3. HAZARDS IDENTIFICATION
*As defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200
See Section 8 for exposure guidelines & Section 11 for toxicology and ingredient specific Information.
**************************Emergency Overview***************************

Pale Yellow Liquid. Mild Amine Odor.
Respiratory Irritant.
Eye Corrosive. Corrosive to the Gastrointestinal Tract.
Moderate Skin irritant.
Respiratory Sensitizer. Skin Sensitizer.

Potential Health Hazards

Eye: This product contains a component (s) which is eye corrosive based on animal studies.
Skin: This product contains a component (s) which is moderate skin irritant based on animal studies. This product is likely to induce sensitization in humans. A component is a known animal skin sensitizer.
Inhalation: Vapors and /or aerosols of this material will probably irritate mucous membranes, eyes, nose and respiratory passages. This product may induce respiratory allergy/sensitization asthmatic wheezing.
Ingestion: In humans, irritation or chemical burns of the mouth, pharynx, esophagus, and stomach can develop following ingestion of this materials, this material is classified as slightly toxic by ingestion.

See Section 11

Section 4. FIRST AID MEASURES
General First Aid Procedures

Eyes:
Immediately flush the eyes with large quantities of running water for a minimum of 15 minutes. Hold the eyelids apart during the flushing to ensure rinsing of entire surface of the eye and lids with water. Do not attempt to neutralize with chemical agents. Obtain medical attention as soon as possible. Oils or ointments should not be used at this time.
Continue the flushing for additional 15 minutes if a physician is not available immediately.
Inhalation:
Remove victim to fresh air. If not breathing give artificial respiration, preferably mouth to mouth. If breathing is labored, give oxygen. Consult medical personnel.
Skin:
Wash off skin with plenty of soap and water. If redness itching or burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before reuse.
Ingestion:
DO NOT INDUCE VOMITING. Give one or two glasses of water to drink and refer to medical personnel or take direction from either physician or a poison control center. Never give anything by mouth to an unconscious person.
Note to Physician:
Mucosal injury following ingestion of this potentially corrosive material contraindicates the induction of vomiting.
Medical personnel should evaluate persons with chronic pulmonary disease before those workers handle this product.

Section 5. FIRE – FIGHTING MEASURES
Flammable Properties:
Flash Point: > 200°F, 93°C Method : Penske-Martin closed Tester.
Upper Flammability Limit (UFL): No Data
Lower Flammability Limit (UFL): No Data
Auto Ignition Temperature: No Data
Products of combustion:
Combustion products: Oxides of carbon and nitrogen.
Extinguishing media:
Water fog, foam, carbon dioxide, dry chemical, halogenated agents. Water may be used to cool closed containers to prevent pressure buildup.
Fire fighting instructions :
Wear self- contained breathing apparatus with full face piece and protective clothing.
Unusual fire and explosion hazards:
Heat / impurities may increase temperature/ build pressure/rupture closed containers, spreading fire, increasing risk of burns/injuries.

Section 6. ACCIDENTAL RELEASE MEASURES
Spill procedures:
Wear skin, eye, and respiratory protection during clean up.
Contain spill.
Soak up material with absorbent and shovel into a chemical waste container.
Decontaminate with 1% acetic acid solution or one part white vinegar to four parts of water.

Section 7. HANDLING AND STORAGE
HANDLING:
Open containers of Wearmax cross linker in well ventilated areas to avoid exposure to residual propyleneimine that may have collected in the head space. Avoid breathing vapors or aerosols. Prevent Skin and eye contact. A sensitized individual should not be exposed to the product which caused the sensitization.
STORAGE:
Keep container tightly sealed. Store in a cool, well ventilated area away from heat, sources of ignition, direct sun light, and acidic materials, anhydrides and strong oxidizers.
Avoid contamination with acidic materials, heat, direct sun light, ultraviolet radiation, strong oxidizing and freezing conditions.

Section 8. EXPOSURE CONTROL/PERSONAL PROTECTION
Exposure guidelines:
No ACGIV TLV or OSHA PEL assigned to this product. Minimize exposure in accordance with good hygienic practice.
Engineering controls:
Use permitted ventilation adequate to maintain safe levels. Provide general dilution or local exhaust ventilation to remove solid airborne particles of over spray during spray application and to remove decomposition products during welding or flame cutting on surfaces coated with this product.
PERSONAL PROTECTIVE EQUIPMENT:
Respiratory Protection: If needed use NIOSH certified respirator for organic vapors , mists and fumes. Any person who may be exposed to this material in the form of aerosol or mist from spray operations shall, at a minimum, wear a National Institute for Occupational Safety and Health-approved, category 21c respirator, excluding single use or disposable types, in accordance with 30 CFR Subpart K. The respirator shall be equipped with high efficiency particulate filters for maximum protection, unless an air-supplied respirator is selected. Use of this respirator shall be according to Occupational Safety and Health Administration and Mine Safety and Health Administration Regulations at 29 CFR 1910.134 and 30 CFR 11, respectively. If a full-face type respirator is selected and worn, the chemical safety goggles requirement is waived during spray operations.
Protective Clothing: Take all precautions to prevent skin contact. Use gloves, arm covers and apron determined to be impervious under the conditions of use. Additional protection, such as full body suit and boots, may be required depending on conditions.
Remove contaminated clothing and wash before rewearing. Wash separately from other laundry.
Trustor employees use neoprene or nitrile gloves during manufacture and packaging of this product.
Eye protection: Chemical tight goggles and full face shield.

Other: Eyewash station and safety shower in work area.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state Liquid
Appearance: Pale yellow
Odor: Mild amine
Odor Threshold: No Data
Boiling Point: No Data
Decomposition Temperature: No Data
Melting Point: No Data
Vapor pressure (mm Hg at 20°C): No Data
Vapor Density ( air = 1 ): > 1
Solubility in water: Dispersible
Solubility in other: No Data
Octanol/Water Partition Coefficient No Data
pH: No Data basic
Specific Gravity: 1.07
% volatile by volume: 1
VOC (%): 0.50
Viscosity: No Data

Section 10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under normal conditions. Unstable at elevated temperatures and pressure, or may react with water or acids with some release of energy, but not violently.
CONDITIONS TO AVOID: Avoid contamination with acidic materials, heat, direct sun light, ultraviolet radiation, strong oxidizing and freezing conditions.
INCOMPATIBILITY: Acidic materials, anhydrides and strong oxidizers.
HAZARDOUS POLYMERZATION: May occur if mixed with acidic materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and nitogen.

Section 11. TOXICOLOGICAL INFORMATION
Contact the address above Section 1 for product toxicology information.

Regulated carcinogen (s)
This product contains no components at concentrations equal to or greater than 0.1% listed by IARC, OSHA, NTP or ACGIH as carcinogen.
Mutagenicity:
Polyfunctional aziridine: Positive mutagenicity activity has been reported on the aziridine compounds.

Section 12. ECOLOGICAL INFORMATION
Eco toxicity: No Data
Environmental fate: No Data
Other: No Data

Section 13. DISPOSAL CONSIDERATIONS
Disposal method: Discarded product is not a hazardous waste under RCRA, but may be regulated by other jurisdictions. Incinerate in approved facility. Do not incinerate in closed containers. Dilute with clean , low viscosity fuel. Untreated material should not be released to the environment.

Section 14. TRANSPORT INFORMATION
Not regulated by the US DOT.

Section 15. REGULATORY INFORMATION
TSCA (Toxic Substances Control Act)
All ingredients are on the TSCA inventory.
SARA title III ( Emergency Planning and Community Right-To-Know Act ):
313 Reportable ingredients:
This product does not contain any chemicals subject to the reporting requirements of SARA section 313.
California Proposition 65:
Warning: This product contains a chemical known to the State of California to cause cancer.

Canadian Regulations:
CEPA ( Canadian Environmental Protection Act ) : All ingredients are on the DSL
( Domestic Substances List )

WHMIS Classifications:
Class D, Division 2A, Very Toxic.
Class D, Division 2B, Toxic.

Section 16. other information

We assigned NFMA and HMIS ratings to this product based on the hazards of its ingredient (s). Because the customer is most aware of the application of the product, he must ensure that proper personal protective equipment (PPE) is provided consistent with information contained in the product MSDS*

NFPA Rating:
Health: 3
Fire: 1
Reactivity 1
Special: No Data

HMIS Rating:
Health: 3 Chronic Effect
Fire: 1
Reactivity: 1
** Personal Protection: No Data

*This information is intended solely for the use of individuals trained in the particular hazard rating system.
** See appropriate MSDS section.
Revision status:
Version number: 0025
MSDS Version date: 03/01/00
Revision: 10

Issue date: 08/08/00
Revision: 11

The information herein is given in good faith but no warranty, expressed or implied, is made.

Prepared by: PJR/EL
Approved by: TW/PJR/KRB/MJB/JG
Approval date: 02/08/00

The information of this MSDS is based on the present state of our knowledge and on current EEC and national laws as the user’s working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified under section 1 without first obtaining written handling instructions. It is always the responsibility of the user to take all necessary steps in order to fulfill the demand laid down in the local rules and legislation. The information in this MSDS is meant as a description of the safety requirements of our product; it is not to be considered as a guarantee of the properties of the product.

Trustor Coatings believes the statements, technical information and recommendations contained herein are reliable. They are given without warranty or guarantee of any kind, expressed or implied.

DATE REVISED: August 03, 2001 PREPARED BY: Trustor Coatings